Electric Vehicles (EV’s) are measured as an excellent replacement for fuel based vehicle due to their limited emission of greenhouse gases. Despite that, it is essential to establish better EV charging system to enlarge EV utilization. Thus, this paper proposes an enhanced EV charging process based on dual PhotoVoltaic (PV) using High Gain Luo converter with optimized PI controller. High Gain Luo Converter is deployed for both PV system for boosting their output power supply, which enables to achieve higher efficiency with improved Voltage gain, power quality with reduced ripples. For attaining enhanced converter performance, Falcon Optimized Algorithm (FAO) based PI controller is utilized which enables faster response rate with reduced steady-state errors with higher quality results. Furthermore, Bidirectional DC-DC (BDC) converter is utilized to attain overall charging and discharging level of EV battery where separate ANN controllers are employed for monitoring and controlling the charging operation as well as bidirectional converter. Moreover, to determine performance proficiency of proposed system, MATLAB simulation is implemented, from which it is remarkable that dual PV powered EV charging system attained higher efficiency of (95.73%), Voltage gain and reduced THD of (2.87). Therefore, this system ensures superior EV charging with continuous power supply and accurate detection of EV charging level.